8/15/2023 0 Comments Atom vs moleculeContinuing this trend, we have another tetrahedral with single bonds attached to Hydrogen and Carbon atoms. Again, we have 4 electron groups which result in a tetrahedral. This Carbon has 2 single bonds to 2 Carbons and 2 single bonds to 2 Hydrogens. By checking the geometry of molecules chart above, we have a tetrahedral shape. That means that we have 4 electron groups. We see that C has three single bonds to 2 Hydrogens and one single bond to Carbon. If we break down each Carbon, the central atoms, into pieces, we can determine the relative shape of each section. You can view a better structural formula of butane at en./wiki/File:Butane-2D-flat.png C-C-C-C is the simplified structural formula where the Hydrogens (not shown) are implied to have single bonds to Carbon. Follow the example provided below:īutane is C 4H 10. In other words, we take long chain molecules and break it down into pieces. For the final description, we combine the separate description of each atom. We take in account the geometric distribution of the terminal atoms around each central atom. The VSEPR theory not only applies to one central atom, but it applies to molecules with more than one central atom. Molecules with More than One Central Atom Geometry of Molecules Chart Number of Electron Groups For example, a molecule with two bond pairs and two lone pairs would have this notation: AX 2E 2. The x represents the number of lone pairs present in the molecule. When lone pairs are present, the letter E x is added. "A" represents the central atom and n represents the number of bonds with the central atom. The VSEPR notation for these molecules are AX n. See the chart below for more information on how they are named depending on the number of lone pairs the molecule has.Īs stated above, molecular geometry and electron-group geometry are the same when there are no lone pairs. When the electron groups are all bond pairs, they are named exactly like the electron-group geometry. Molecular geometry, on the other hand, depends on not only on the number of electron groups, but also on the number of lone pairs. ![]() We separate this into two categories, the electron-group geometry and the molecular geometry.Įlectron-group geometry is determined by the number of electron groups. Although VSEPR theory predicts the distribution of the electrons, we have to take in consideration of the actual determinant of the molecular shape. ![]() Thus, the molecule's shape reflects its equilibrium state in which it has the lowest possible energy in the system. The electrons and the nuclei settle into positions that minimize repulsion and maximize attraction. The shape of a molecule is determined by the location of the nuclei and its electrons. Using the VSEPR theory, the electron bond pairs and lone pairs on the center atom will help us predict the shape of a molecule. An electron group can be an electron pair, a lone pair, a single unpaired electron, a double bond or a triple bond on the center atom. ![]() VSEPR focuses not only on electron pairs, but it also focus on electron groups as a whole. Thus, electron pairs will spread themselves as far from each other as possible to minimize repulsion. The valence-shell electron-pair repulsion (VSEPR) theory states that electron pairs repel each other whether or not they are in bond pairs or in lone pairs. Now that we have a background in the Lewis electron dot structure we can use it to locate the the valence electrons of the center atom. Valence-Shell Electron-Pair Repulsion Theory Electrons and neutrons may be present, but aren't required.\( \newcommand\) At its most basic level, an atom is any particle of matter that contains at least one proton. Many atoms consist of a positively charged nucleus composed of protons and neutrons surrounded by a negatively charged cloud of electrons. Protons and neutrons are similar in mass, while electrons are much smaller and lighter. The building blocks of atoms are positively charged protons, neutral neutrons, and negatively charged electrons.
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Here, Izzo-the Chilean-born actress who also stars in the recent thriller The Green Inferno-explains the draw of scary movies and why a simple haircut might have been the most terrifying scene of her career. ![]() What follows is a tense, frightening game of cats-and-mouse that makes it clear nothing a viewer thinks he knows about anyone involved is even remotely true. ![]() However, they used the original version in the final cut of Knock Knock, and Reeves said that he felt it was the right decision.In Knock Knock, the enthralling new horror film by director Eli Roth, two young women (Lorenza Izzo and Ana de Armas) appear at the door of an architect (Keanu Reeves) whose family has gone away for the weekend. He wasn't wanting the other rending uses, he just wanted to play with his reaction when it came to screaming, almost a plea and a form of self-defense from his character. When looking at the Knock Knock alternate ending, Keanu said the ending with him screaming at the women and asking why they did this to him, he said that he asked for that shot to be re-filmed. In terms of the big picture there was no like, “Oh that scene got cut,” or, “Maybe this should go here,” really." We rehearsed so much that basically we were all off book and it basically turned into a play. If anything, it was we rehearsed for 4 or 5 days in the house. He mentioned how the main focus was for Eli Roth to plan out the shots and cancer angles with the cinematographer and the actors would just perform the scenes without changing them too much. When it came to Roth making any changes, especially concerning the alternate ending, Reeves said that the director changed almost nothing that was planned. Keanu Reeves talked a lot about Knock Knockand any differences between the original script and the movie itself (via Collider). The Knock Knock alternate ending would have been more sensible and offered the story several additional layers that it desperately needed. In Knock Knock's theatrical ending, the audience can assume Evan's wife leaves him, and the suffering he faced continues to impact his life. It could've added nuance to a movie that, as it stands now, has a simplistic ending. Had it concluded with Eli Roth's alternate ending, it could've expanded the story beyond the assumption that Genesis and Bel are just senseless brutalizers. However, this ending likely wouldn't have sent the right message, given Bel and Genesis' potential backstory.Īt its core, Knock Knock is a story about victims, survivors, and predators. When he knocks on the door of their next victim's home, it could've given him the ability to find answers or enact revenge on them for ruining his life. Evan represents something evil from their past that Bel and Genesis cannot escape it's clear that the two women went through something awful in their lives, which in turn caused them to turn their tormentors into their victims. Their reasoning for targeting men like Evan is never fully revealed, but it could've been, had the Knock Knock alternate ending offered the opportunity for a sequel. 8/15/2023 0 Comments Dallas cowboys roster 2005![]() ![]() Following a loss to the Baltimore Ravens, Drew Henson would start the annual Thanksgiving Day game against the Chicago Bears. Dallas' defense would also regress from the previous season, especially the secondary which lost starting cornerback Mario Edwards in free agency and longtime mainstay and team leader safety Darren Woodson due to injury. His extensive experience and veteran presence was an asset to the team, especially to young undrafted practice squad addition Tony Romo, but failed to produce many points behind an inconsistent offensive line. Vinny Testaverde would be the opening day starter for the Cowboys. When Carter left, Romo moved up to number 3, and was later a Pro Bowl starting quarterback for the Cowboys. This move had a long-term effect on the team: Had Carter remained, second-year QB Tony Romo would have been fourth on the depth chart and likely cut from the team. ![]() Carter's formal protest of his release through the NFLPA as well as his subsequent troubles with drug addiction appear to lend credence to this scenario, According to the NFLPA. A third violation of the substance abuse program results in a mandatory suspension, and the Cowboys, unwilling to risk losing a starting quarterback during the season, began to monitor Carter with its own drug tests. Test results are not made public but notices are sent to team officials. Rumors began that Carter had already entered the second phase of the NFL's substance abuse program, meaning he had twice failed NFL-mandated random drug screenings. Though never verified by Carter or the team, it has been speculated by the Cowboys, that his release was prompted by a failed drug test administered by the Cowboys, an action prohibited by NFL rules. The move came with no warning reporters at training camp became aware something had occurred when Carter did not suit up for practice and was later seen being escorted from the Cowboys facility. Within the first week of camp, the Cowboys released starting quarterback Quincy Carter. With the opening of training camp, the team seemed poised to take the next step however, this soon changed. His struggles in the New York Yankees farm system led him to reconsider his career and opt for a return to football, similar to Chad Hutchinson, whom the team had acquired two years prior. Henson starred at Michigan, keeping future NFL quarterback Tom Brady from claiming the starting job outright. In owner Jerry Jones's continuing quest to acquire quarterback talent, the Cowboys traded for the rights to Drew Henson, another baseball player attempting to return to football. The draft saw the arrival of running back Julius Jones, cornerbacks Jacques Reeves and Nate Jones, and college quarterback turned wide receiver Patrick Crayton. In return for Johnson, the Buccaneers received Joey Galloway. Both Testaverde and Johnson had played for Parcells when he had coached the New York Jets. In the offseason, the Cowboys signed quarterback Vinny Testaverde and traded for wide receiver Keyshawn Johnson. Coming off their first winning season for the first time in five years, the team, under Bill Parcells' direction, continued to bring in veteran talent and draft promising prospects. Offseason īefore the season began, the Cowboys faced were forced to adjust. The team failed to improve on their 10-6 record in 2003 and finished at 6–10, failing to make the playoffs for the fourth time since 1999. ![]() The 2004 season was the Dallas Cowboys' 45th in the National Football League (NFL), their 16th under the ownership of Jerry Jones, their 33rd playing their home games at Texas Stadium, and their second season under head coach Bill Parcells. ![]() The Legion 5i Pro earned 99 fps at 1080p and 67 fps at 1440p, the Razer Blade got 76 and 58 fps, and the Aero hit 78 fps and 28 fps. Once again, the Legion 5i Pro had the best results by a slim margin (110 and 69 fps, respectively), with the Razer Blade and Gigabyte Aero not too far behind the Predator.įinally, on the Borderlands 3 benchmark (badass settings), the Predator managed 87 fps in 1080p and 60 fps at 1440p. When we ran the Shadow of the Tomb Raider benchmark (highest settings), the Predator achieved 98 fps at 1080p and 65 fps at 1440p. As usual, the Legion had slightly better performance, while the Razer and Aero underperformed. On the Red Dead Redemption 2 benchmark (medium settings), we saw the Predator output 72 fps at 1080p and 50 fps at 1440p. However, the Gigabyte Aero 16 had a higher 89 fps at 1080p. ![]() ![]() The Legion 5i Pro hit 88 fps at 1080p and 70 fps at 1440p, and the Razer Blade 15 was just a few frames behind it. However, the Gigabyte Aero 16 and its RTX 3070 Ti (with 16 GB VRAM) underperformed with 101 fps at 1080p and 28 fps in its native 4K resolution.ĭuring the Far Cry 6 (ultra settings) benchmark, the Predator reached 82 fps at 1080p and 67 fps at 1440p. The Legion 5i Pro outperformed the Helios with 131 fps at 1080p and 78 fps at 1440p, while the Razer Blade 15 reached 104 fps at 1080p and 67 fps in its native resolution. ![]() When we ran Grand Theft Auto V’s benchmark at very high settings, the Acer Predator Helios 300 played at 117 fps at 1080p and 77 fps in native 1440p. With DLSS and V-Sync turned on, the game jumped to a more consistent 145 fps. As I stalked a Tigrex, exhausted after the beating I gave it with my Hunting Horn, the game fluctuated between 119 and 129 fps. While playing Monster Hunter Rise (high setting) with unlocked frame rates at the Helios’ native resolution, the game ran at 139 frames per second. Even though its competitors have the same GPU, the Helios didn't top our tests. Our configuration of the Acer Predator Helios 300 came with an Intel Core i7-12700H CPU, alongside an Nvidia GeForce RTX 3070 Ti that has 8GB of GDDR6 VRAM, a 150W max graphics power, and a 1,410 MHz boost clock. Gaming and Graphics on the Acer Predator Helios 300 Please message us if this happens so we can manually approve your post.Nvidia GeForce RTX 3070 Ti Laptop GPU (8GB GDDR6) 1,410 MHz Boost Clock, 150W Max Graphics PowerĢx USB 3.2 Gen 2 Type-A, USB 3.2 Gen 1 Type-A, Thunderbolt 4, HDMI 2.1, Ethernet, 3.5mm headphone jack, Mini DisplayPort, lock slot If your post or comment contains a link to Amazon it might be caught in the spam filter, which is not something moderators have control over. Please ask permission before posting a survey. Rule#6: Survey links will not be allowed unless they are directly related to gaming laptops. Rule#5: FALSE REPORTING ANYONE OR POSTS WILL RESULT IN A BAN Rule#4: SUBMISSION GUIDELINES MUST BE FOLLOWED OR THE POST WILL BE REMOVED Rule#3: THIS SUBREDDIT IS ABOUT GAMING LAPTOPS NOT ANYTHING ELSE! Rule#2: No Spamming Anyone For Any Reason! Please make sure you read everything before posting! Also the rules are explained in dept on the wiki so read that too! Result of the above survey will be posted publicly on our subreddit upon its conclusion, so fill it out to help current and future users! 8/15/2023 0 Comments Tableau online vs publicServers are not maintained through users but through Tableau guys. They should be kept on the Tableaus public cloud, which can be accessed and viewed. Tableau Public - A huge Tableau server, which hosts a public gallery of vizzes built by people around the world. Get started with your career in analytics by learning Tableau. Tableau Online:– I haven’t used Tableau online however it is an alternative to Tableau Server wherein the servers are on Cloud. The word Public means that the created workbooks cannot be saved locally. Tableau is a popular data visualization, reporting, and business intelligence tool and this free Tableau course will take you right from its basics to advanced topics. You can most effective use restrained information, can only join excel or textual content document (no database connectivity) & whatever you shop in Tableau Public can be stored on Tableau Public Sever which everybody can download. Visualization Enthusiast can play with facts the use of Tableau Public. I spend most of my day with Tableau Desktop, but Tableau Server (and Online and Public) are fun too Tableau Tip Tuesday: Always Manually Backup Tableau Server. Tableau Public:– It’s a loose product from Tableau. When you upload(submit) a Dashboard to Tableau Server from Tableau Desktop, other users can get the right of entry to the one’s Dashboards through going online Tableau Server. Tableau Server:- The dashboards you create are shared with other customers the use of Tableau Server. With more than 3 million profiles and 7 million vizzes, Tableau Public is an engaged and growing community of data enthusiasts creating the largest. Get started for free with web authoring or download Tableau Desktop. ![]() Sign up for a free Tableau Public account. Tableau Reader: It can read the view, here we can view and do interactions. Tableau Public: Open source and any one can download and view your data. Tableau online hosted in tableau software. From creating reports, charts, formatting them, setting them collectively as a dashboard all the paintings are carried out on Tableau Desktop. Explain what Tableau Public is and what its for. Tableau online: Very limited data source connection, mainly focus cloud based datasources. ![]() there is a LOT and there's new features being added all the time.Tableau Desktop:- All your development is finished right here. We're not dumb at all, and I can teach people enough to get certified in less than 6 months - but that's not EVERYTHING in Tableau, you may not ever learn everything because across Prep, Desktop, Server, Online, Public, APIs, etc. Tableau Online: It is a private version of tableau public which. They're thinking the answer is "a couple of weeks up to 6 months" they get upset sometimes when I saw I haven't learned everything in 7yrs, I know people that haven't learned everything in 10yrs. Tableau Server: It is more of a enterprise level Tableau software. I also joke (sometimes) when teaching Tableau when people ask how long does it take to learn Tableau. The BIG difference in Tableau is that you can learn and be as good (or better) over time, and sometimes that timeframe isn't that long. Because I know how to drive, but I don't know anything compared to them. 761566 When viewing a story published to Tableau Online, Tableau Server 10.5.2, or Tableau Public using Safari on a Mac, text in the dashboard textboxes was being cut off with ellipses despite word wrap being set to On or Automatic. ![]() So how are people doing this? Maybe it's like driving a car - have you been driving for a year or 10 yrs ? Do you know how to drive ? No, I mean REALLY know how to drive ? No, I mean do do you know how to drive like Lewis Hamilton drives, or Scott McLaughlin or Shane van Gisbergen drives. In Tableau Online, sometimes viz-in-tooltips failed to load. They use web connectors to connect databases that publish in HTML forms. Viewers can then access them like a webpage. VOTD can be created in Tableau Desktop or Tableau Public and then published to the website. Tableau Public is the name of the free version of the desktop solution. It allows you to publish your workbooks and dashboards online. Tableau Online enables users to publish dashboards and invite colleagues to explore hidden opportunities with interactive visualizations and accurate data, from any browser or mobile device. Sure, the connections are a LOT different and if you're using Tableau Publis website then you don't have any of the Server/Online features. Tableau Online is a self-service analytics platform that is fully hosted in the cloud, making it easily accessible. I don't think there's any feature difference when you're "in the tool". 8/14/2023 0 Comments Ascension of jesusThe Holy Spirit is also mentioned in the second reading as the source of wisdom and revelation that helps believers understand the hope to which they have been called. Holy Spirit: In the first reading, Jesus tells his disciples that they will receive power when the Holy Spirit comes upon them.This is emphasized in the Great Commission as disciples are called to go out to all nations. Getting out of our comfort zones: Making disciples often requires stepping outside of one’s comfort zone and engaging with people who may have different backgrounds, cultures, or beliefs.The Great Commission in all three passages emphasizes the importance of evangelism as part of making disciples. Evangelism: This is the act of sharing the good news of Jesus Christ with others.This emphasizes the importance of reaching out beyond one’s own community to share the message of Jesus Christ. The Great Commission requires the disciples to go out into the world and make disciples of all nations. The Great Commission: This is a command given by Jesus to his disciples to go out to the world and make disciples of all nations.The second reading speaks of the ascension as an exaltation of Jesus Christ, who is now seated at the right hand of God in heaven, with power and authority over all things, and is a source of hope and enlightenment for believers. Before his ascension, Jesus told his disciples to stay in Jerusalem and wait for the promised Holy Spirit to come upon them. The Ascension: The first reading for the Ascension of the Lord Year A tells us that Jesus appeared to his disciples over a period of forty days after his resurrection and taught them about the kingdom of God. ![]() And in the gospel, Jesus tells his disciples to preach the Good News to the whole world. In the second reading we hear that Jesus Christ rules heaven and earth. In the first reading the ascension of Jesus is recounted and the Apostles are told they will receive the Holy Spirit. He also gave the Great Commission, that all of the world should be saved. The feast of the Ascension of the Lord Year A commemorates the day that Jesus Christ ascended into heaven. ![]() Themes for the Ascension of the Lord Year A Jesus commissions his disciples to go and make disciples of all nations, baptizing them in the name of the Father, Son, and Holy Spirit, and teaching them to obey everything he has commanded.
8/14/2023 0 Comments Kreg screw guideWhile not absolutely necessary, I highly recommend a vacuum attachment. Again, this is an adjustment I rarely have to change. Lock the collar by tightening the set screw. This will keep it from drilling into the plastic. Use an Allen wrench to loosen it.ĭrop the drill bit into one of the guide holes until the tip touched the plastic base. The drill bit comes with an adjustable collar that is held in place with a set screw. I hardly ever have to adjust this because I mostly use 3/4″ lumber when making pocket holes. I use the K5 jig.įirst, set this drill bit guide part to match the thickness of your board. They both accomplish the same task, but the K5 is a little easier to set up and adjust. There are two versions: the K4 and the newer K5. There are other brands of pocket hole jigs, but the Kreg Jig is clearly the king and the only kind I have every used. ![]() Additionally, this may actually be stronger than screwing straight into face grain, because the angle will ensure a longer portion of the screw will be embedded in the wood. The solution is to drive a screw at an angle so that it goes into the face grain (or edge grain) of each board. The important thing to always keep in mind, whether you are using pocket screws or not, is that screwing into the end grain of a board provides the weakest connection.įor a project that won’t be subjected to a lot of stress, screwing into the end grain can work, but a far better choice is to avoid this practice, especially when using softwoods such as pine. It’s good to understand good grain and direction to learn how pocket screws work. It’s a big community and there is plenty of room for all of us! How Pocket Hole Joinery Works We can awe at the work of others and get inspired by their approaches and goals. Of course most of us are somewhere in between and that’s what makes woodworking interesting. These folks are more interested in completing a project they can use, rather than relishing in the shop experience. At the other end of the spectrum are the “project based” makers. Quiet time in the shop can be a centering, healing experience. ![]() Spending time perfecting difficult skills and procedures can be personally satisfying and enjoyable. Some people find that the process alone is woodworking’s greatest reward. There is a wide spectrum of building and woodworking. While I am not interested in getting deep into this topic here, it is pretty hard to discuss pocket holes without touching on it. ![]() Some people will argue that pocket screws are “cheating” and the only proper way to build is by spending countless hours practicing and refining techniques such as mortise and tenons, or hand cut dovetail joints. Anyone can purchase a relatively inexpensive pocket hole jig and start building immediately! It’s not just a great introduction into woodworking, but a great technique for experienced builders too. Over the past decade, pocket hole joinery has enabled millions of people to make strong, great-looking furniture and other projects without years of training or experience. 8/14/2023 0 Comments Dirt 4 mac![]() Continued abuse of our services will cause your IP address to be blocked indefinitely. Please fill out the CAPTCHA below and then click the button to indicate that you agree to these terms. If you wish to be unblocked, you must agree that you will take immediate steps to rectify this issue. If you do not understand what is causing this behavior, please contact us here. Use the indicated client to activate key and download and play your game. Head over to one of the trusted game stores from our price comparison and buy cd key at the best price. If you promise to stop (by clicking the Agree button below), we'll unblock your connection for now, but we will immediately re-block it if we detect additional bad behavior. Compare prices with GG.deals to find the cheapest cd key for DiRT 4 PC.
8/14/2023 0 Comments Resume builder readwrite think![]() ![]() Many people think of cover letters as a way for the writer’s true voice to come through. They personalize the resume, allowing the writer to provide more detail about him- or herself and any relevant experience. Function: Cover letters accompany resumes to introduce the reader of the resume to the writer.What do you like or dislike about your completed resume? d.What did you find particularly easy or difficult about the process?.What did you like about using Resume Builder to create your resume?.Have students take out the resumes they created using Resume Generator during Lesson 4.They can do this individually or in small groups. Printout to fill out and bring to the next class. Give them the Visualizing Your Resume: Graphic Organizer ![]() Ask students to comment on how these are related and why they are important. The purpose refers to why the audience is looking at the resume and what they will be looking for, so we must ask ourselves what they want to read.Ĭonnect audience and purpose to the 3Fs as discussed in the previous class.The audience refers to anyone who will review the resume, so we must consider all audiences, both primary and secondary.Begin a discussion about the importance of audience and purpose when creating a resume, as these are fundamental items to consider when putting all of their information together.What sections contained the most and least information? Why?Īsk for volunteers to share what they included in each section with the class.What was easy about filling this out? What was difficult?.Bring the class back together and ask students questions about their process.Put them into small groups to share their work with others. Have students take out their completed My Resume Ideas: Getting Started.Return together as a class, and discuss each F and how students determined what it was.Tell them to identify what they see as the 3 Fs: Function, Form, and (e)Ffectiveness. You might begin discussing these by putting students into small groups first to review. Is grammatically correct with no errors in punctuation or spelling Includes all the necessary information about the writer Is visually appropriate and appealing, or easy to read Has a clear purpose that shows why you are writing it (e)Ffectiveness: For a resume to be effective, it must demonstrate your knowledge of both function and form.If a resume does not look like a traditional resume, the reader may be confused and think the writer is not educated about writing proper resumes. People who read resumes expect them to include specific information, such as your name, address, contact information, education, past jobs, volunteer experience, and special skills. Form: Resumes need to look a certain way. ![]() There are many reasons to show people your resume. This might include getting a job, getting into college, winning a scholarship, or being selected for an internship. What you’re trying to accomplish depends on what you’re trying to do.
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